The point radio sources comprise one amongst the major contaminants of the Cosmic Microwave Background radiation. Consequently, they possess a significant potential for causing severe distortion of the information imprinted in its anisotropies. They demand therefore some sort of treatment that usually boils down to removing contaminated pixels in any CMB experiment. As a support to the Cosmic Background Imager (CBI) we have carried out intensive observations of a sample of nearly 6000 NVSS sources that happen to be in the targeted fields at two frequencies (4.85 and 10.45 GHz) with the 100-m telescope at Effelsberg. The objective has been the estimation of the flux density that each one of them could contribute at the central frequency of the CBI (31 GHz) on the basis of their three-point radio spectral index and their 1.4-GHz flux density as extracted from the NVSS catalogue. However, the compilation of such an extended data base of multi-frequency measurements gives handle for a series of further studies. First, we exploit the sample in order to compute the source counts at different frequencies. That provides the opportunity for comparison with direct surveys at those wavelengths and more importantly with the theoretical predictions. Practically, this can assist the computation of the confusion limits that set a physical limit to the reachable sensitivity of radio instruments. Further, the computed spectral indices have been used to trace candidates for GHz-Peacked Spectrum sources and their extreme sub-class of High Frequency Peakers that are believed to be the early evolutionary stages of radio activity. Additionally, although the observations have been designed to be time-efficient we manage to carry some polarization studies. The main aspects of those matters will be discussed.